You mean like any other machine that generates power? A human on a bicycle, assuming a ~20% efficiency of converting food calories to muscle output, gets a gasoline equivalent 600-1000mpge (https://en.wikipedia.org/wiki/Bicycle_performance). And unlike a car, using a bicycle has health benefits.
The leading vehicles in the Shell Eco-marathon routinely exceed 10,000 MPGe. PAC-Car II is the current world record holder, achieving 12,600 MPGe on hydrogen fuel.
Photovoltaic cells are also astonishingly more efficient than photosynthesis. The theoretical maximum efficiency of photosynthesis is ~11%, but most plants only achieve 3-6% efficiency. The leading commercially-available PV panels achieve ~22% efficiency and prototype concentrator PV cells have achieved over 46% efficiency.
(0.024 l/100 km, 0.019 l/100 km)
(0.24 - 0.4 l/100 km)
The thing about human power is that exercise is also good for us, and in our current times most people (at least in developed countries) don't really get enough of it. So it doesn't necessarily have to be the most efficient to be useful.
You'll have to use energy to produce and distribute the food that powers the people that power the things...
Perhaps you would be better off if you simply used the energy to power the things.
It would reduce my stress to imagine a world where my grandchildren didn't die from atrophy during the great power outage of 2079, where only the 10% of humanity that weren't reliant on exercise machines exercising their muscles for them, survived.