No, in C a NULL pointer dereference is not a crash, it's undefined behavior (which yes, can manifest as a crash), which is much more unpredictable.
For anyone still believing a NULL dereference (or any of the other UB that is in the C spec) is just a segfault, "What Every C Programmer Should Know About Undefined Behavior" is still required reading:
http://blog.llvm.org/2011/05/what-every-c-programmer-should-...
Here's how triggering UB ends up as a vulnerability:
To be fair, dereferencing NULL ended up as a vulnerability due to
1. the optimiser removing the subsequent NULL check, and
2. the zero page being mapped.
While 1. may happen, depending on how sophisticated the compiler is, 2. was already a security issue and is 'almost always' not the case.