It's nearly impossible to retroactively disclaim things submitted through such varied means. So the safest course of action is just to send things back, or disregard them altogether. If someone's really written a brilliant masterpiece, then he should get an agent and go in through that door.
It's an imperfect system, but it's a system born of necessity. Even big networks typically have scripted development staffs of no more than 10 to 15 people (sometimes considerably fewer), all of whom are spending 100% of their time working on existing projects, or hearing pitches from agencies and producers. These people don't have time to read everything that comes their way through the mail, even if they wanted to, and even assuming that more than 1% of what comes in unsolicited is actually worth reading. And none of them wants to bear any legal liability. (Imagine greenlighting a show about superheroes, then opening a random envelope and finding a pitch that's very similar; talk about a potential "Awww, fuck" headache moment).
but also impossible to prove.