The Central Limit Theorem (which says if we add a bunch of random numbers together they'll converge on a bell curve) only guarantees that you'll get a normal distribution. It doesn't say where the mean of the distribution will be.
Correct me if I'm wrong, but if your resistor factory has a constant skew making all the resistances higher than their nominal value, a bunch of 6.8K + 6.8K resistors will not on average approximate a 13.6K resistor. It will start converging on something much higher than that.
Tolerances don't guarantee any properties of the statistical distribution of parts. As others have said, oftentimes it can even be a bimodal distribution because of product binning; one production line can be made to make different tolerances of resistors. An exactly 6.8K resistor gets sold as 1% tolerance while a 7K gets sold as 5%.