I don't want to learn a new language just to configure my editor.
So by choosing scheme they essentially say this is an editor for computer scientists only. </controversial opinion>
But when you're just configuring software this heavily dynamic nature becomes a strength. I just need to build the abstractions in my config that I need, nobody else. It's easy to poke around in and spend a few minutes writing and iterating on code to get the config I want.
I agree that the prefix notation and the soup of parentheses give it a higher learning curve than something like Lua which is easily understandable if you have experience in pretty much any modern programming language. But it's not the mathematical/computational purity that makes Lisps appealing, it's their highly dynamic nature.