Look in the digital forensics industry. Field forensic investigators can get bags or boxes (look like Pelican(r) cases), or inserts for Pelican cases (a 1615 fits just right into a sedan's trunk).

Long time ago when mobile forensics was in its infancy they were given out as swag.

The #1 problem is of course that if not in airplane mode, some not too smart phones keep increasing the power to the radio (smarter ones do this for a few minutes then power down radio, then cycle up again). Guess what happens with a bunch of juice dumped into electronics in a locked case inside a trunk in a hot car, with half dozen other phones doing the same thing (because it is never a single burner phone).

In a pinch, 3 to 5 layers of aluminum foil, stainless steel cocktail shaker, ammo can, or combination thereof works.

edit: Yes, if we are discussing this with physicists, RF cannot be blocked, it can be attenuated. The strength of the RF signal is reduced as it travels through different materials, and in theory it can never be completely eliminated. In practicality, the signal only needs to be attenuated until it cannot be picked up sufficiently even when very close by a receiver.