First, for hair rendering you've got a 3D trajectory, which Béziers can handle just fine, but I'm not sure about these spirals. I do have a chapter in my thesis and there has been a bit of followup from others, but I can't say anything with confidence.
That said, because of the specular reflections, applications like hair really would benefit from higher degrees of continuity. Cem Yuksel has a recent SIGGRAPH paper on how to tweak Béziers to get more continuity. In fact, seeing that was one of the motivations to take this work off the back burner.
I'm not sure about maps. But I do know of applications representing the centerline for autonomous vehicles that use polynomial spiral representations, specifically because of the extremely high degrees of continuity you can attain. For that, you don't have to represent these high-tension curvature regions.
I do think there is a specific application for drawing smooth connecting lines in autogenerated diagrams. These tend to be S-shaped, and with Béziers you tend to get curvature peaks near the endpoints. You're much better off with monotonic curvature and with spirals that's easier to achieve. And I also believe being able to get those squircle/superellipse shapes would help as well.