http://www.nsf.gov/statistics/seind14/index.cfm/chapter-5/c5...
Thailand and Mongolia versus South Korea and Taiwan. Canada versus the US. Portugal versus Spain.
Once you select specific disciplines a lot of the countries have extremely small relevant populations though.
Ukraine have more women than men in term of sex ratio. So of course there is more phd awarded to women than men.
There are tons of debates on how there are less female in engineering and such but I have yet to see a reason why that is. It could be anything including something innoculous. If there is a systematically evil group that is trying to prevent women from going into CS then I am all for stopping them. But if because the women themselves just chose to do other things than CS than who am I to try to change their mind?
"How Nations Fare in Sex by PhDs"